I would like to know under what circumstances is Trouton's rule obeyed by liquids and why certain systems i.e. substances may deviate from Trouton's rule.
By the way I know what Trouton's rule is and I have a vague idea that sometimes Trouton's rule is not obeyed due to the presence of hydrogen bonding in liquids such as water but I would like to know more about other reasons why certain situations the rule is invalid.
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