Monday, April 2, 2018

inorganic chemistry - In Crystal Field Theory what does Δo=10Dq mean?


While studying the Crystal Field Theory I was told $\mathrm{Dq}$ is a unit, related to the unit $\Delta_{\mathrm{O}}$ by the relation $\Delta_{\mathrm{O}} = 10\ \mathrm{Dq}$. But aren't $\Delta_{\mathrm{O}}$ and $\mathrm{Dq}$ variables, not units? The unit is of energy, such as $\mathrm{eV}$ or Joules, these are symbols to represent a particular value of energy, which could be anything. So what do we mean when we say $\Delta_{\mathrm{O}}= 10\ \mathrm{Dq}$? What exactly is $\mathrm{Dq}$ (I haven't been able to find this in any of my textbooks, they just either state this relation, or not at all) and are they actually units of energy?




No comments:

Post a Comment

digital communications - Understanding the Matched Filter

I have a question about matched filtering. Does the matched filter maximise the SNR at the moment of decision only? As far as I understand, ...