Sunday, December 10, 2017

Are fractional oxidation states possible?


To get the oxidation state of carbon (denoted $x$) in octane, $\ce{C8H18}$, I used the fact that hydrogen has an oxidation state of $+1$:


$$8x + 18\cdot 1 = 0 \qquad \Longrightarrow \qquad x = -\frac{18}{8} = -2.25$$


But in that way, I get an oxidation number that is fractional, or not an integer. Is that normal?




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