Sunday, December 31, 2017

homework - Acidity In Organic Compounds


Why is the acidity order true? CHX3COCHX3>CHX3COX2CHX3>CHX3CON(CHX3)X2


I deduced that in second and third option there is a I effect of the methoxy group, N(CHX3)X2 and a +R effect, too so the attached keto-carbon develops a positive charge and the conjugate base becomes unstable due to the +R effect of methoxy and N(CHX3)X2 groups.


Is my logic right?


Please tell me any explanation you can think of.




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