For example:
- て+つな=たづな(手綱)
- め+ふた=まぶた(瞼・目蓋)
- かね+つち=かなづち(金槌)
The only thing I can see for sure is that the second word becomes voiced, but that's more of an after-the-fact thing than a rule that dictates when the sound actually changes from e to a.
Is there a rule or pattern to it?
Answer
e does not become a. Rather, it is the other way around: a becomes e. More specifically, there are two forms of e: e1 and e2. (See 上代特殊仮名遣) The rule is a + i > e2. Both e1 and e2 merge into e after Nara period.
For reference, these pairs are termed 被覆形 and 露出形. The form without the -i suffix is 被覆形 while the -i suffixed form is 露出形.
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