Friday, December 22, 2017

Why does magnesium form covalent bonds with carbon?


According to my professor, magnesium and lithium form covalent bonds with carbon but calcium does not. He did not elaborate.


Why is this so? The electronegativities are:


Mg — 1.31
Li — 0.98
Ca — 1
C — 2.55


So a CMg bond would have an electronegativity difference of 1.24 and a CLi bond would have an electronegativity difference of 1.57. Both are considered covalent. So how come a CCa bond wouldn't be covalent? There exists an electronegativity difference of 1.55 — comparable to the difference in the CLi bond.


I know that Mg likes to be tetra-coordinated (Grignards) but I don't think this has much to do with this discussion. So, what makes Mg and Li special compared to Ca?


Summary of possible explanations others have come up with




  1. MgX2+ has an ionic radius 72 pm, CaX2+ has an ionic radius of 100 pm, and for LiX+, it's 76 pm. So perhaps the greater charge density of MgX2+ and LiX+ allow them to pull electrons toward themselves a bit more, thus making the bond more covalent in character? That being said, LiX+ has a single positive charge while CaX2+ has a double positive charge, and I haven't calculated the actual charge densities for any of these ions so I don't think we can come to a definitive conclusion here.


http://www.wiredchemist.com/chemistry/data/metallic-radii




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