I was fiddling around with Chem3D and the MM2 calculation for finding a molecules minimized energy.
Benzene was assigned a total energy of -0.5741 kcal/mol while biphenyl was assigned a total energy of 4.5397 kcal/mol.
What is the "total energy" relative to? In other words, why does benzene have a negative total energy while biphenyl has a positive total energy? What is the 0 energy state that they are being compared to?
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