Sunday, January 21, 2018

organic chemistry - What is the meaning of n in n-octane and similar compounds?


Straight-chain octane ($\ce{CH3(CH2)6CH3}$) is also called n-octane. What does the n stand for, and where did the term originate?


For reference, see the PubChem entry for octane (beside "Chemical Names:")



Answer



In this case, n means "normal", i.e. straight chain. This is somewhat of a holdover from the olden days, but in the case of octane in particular, it makes sense to specify n-octane if that is what you have. For example, the "octane" used as a standard gasoline engine fuel against which gasolines are rated (by definition, 100 octane) is actually not n-octane, but rather 2,2,4-trimethylpentane - a branched isomer of octane - in contrast to the straight chain version.


Isomers of octane


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