Tuesday, August 27, 2019

physical chemistry - Why will A atoms diffuse from β phase to α phase and B atoms from α phase to β phase?




Molar free energy plot


At the initial compositions 1 and 2 of α and β respectively the chemical potentials of A and B atoms in each phase can be found by extrapolation of the tangents to the free energy curves at 1 and 2 to the corresponding sides of the free energy diagram, as shown above.


All atoms diffuse so as to reduce their chemical potential. Therefore, A atoms will have a tendency to diffuse from α to β (μαA>μβA) and B atoms will have a tendency to diffuse from β to α (μβB>μαB)



The point marked 1 and 2 are basically the compositions of two metal alloys that have been welded. Now annealing is performed at a particular temperature T1 to bring about the change now why will A atoms diffuse from β phase to α phase and B atoms from α phase to β phase?


How will drawing a common tangent be different in interpretation than drawing two individual tangents at compositions 1 and 2?




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