Thursday, December 13, 2018

inorganic chemistry - Is [Co(NH₃)₄Cl₂]Cl paramagnetic or diamagnetic?


$\ce{NH3}$ is known to be a strong field ligand, while $\ce{Cl}$ is known to be a weak field ligand.


Is $\ce{[Co(NH3)4Cl2]Cl}$ a high spin complex or a low spin complex?


I assumed this to be a high spin complex. Oxidation state of $\ce{Co}$ is $+3$. And electronic configuration of $\ce{Co(III)}$ is $\mathrm{[Ar]~3d^6}$.


Since I assumed this to be a high spin complex — pairing of electrons of $\mathrm{3d}$ orbitals will not happen. The $6$ pairs of electrons from the ligands must be included in the $\mathrm{4s}$, $\mathrm{4p}$, $\mathrm{4d}$ orbitals — which leaves electrons unpaired in the $\mathrm{3d}$ orbital, making this a paramagnetic complex, with hybridisation $\mathrm{sp^3d^2}$.


Answer given to this question says otherwise. Hints are welcome!



This question is an excerpt of a question that appeared in the JEE(A) - 2016




No comments:

Post a Comment

digital communications - Understanding the Matched Filter

I have a question about matched filtering. Does the matched filter maximise the SNR at the moment of decision only? As far as I understand, ...