Monday, December 24, 2018

What is the Lewis structure for HClO?


In many sites, I see that they put O in the middle, but our teacher said that we should put O near the extremity. Which is the best way?



Answer



The issue is that HOCl will dissociate, as usually, into HX++OClX, which can only be possiblbe because Cl is formally ClX+ and not the expected ClX. If O was to be put in an extremity, one would end up with OHCl, which makes no sense because H cannot make two bonds, or OClH, which makes no sense because HCl exists independently.


Hypohalous acids, like HOCl, are a point of entry into the "weird" chemistry of halides, which at least in Euopean countries I know is not covered until late in college.


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