Monday, November 6, 2017

kinetics - Do coefficients matter in rate law?


For reaction $\ce{2A→B}$ (elementary step), according to the rate law, rate $= k [A]^2$.


In some calculations, we use $k[A]^2$ as the production rate of B. Why isn't it ${1 \over 2} k[A]^2$?



In this case, is the consumption rate of A also $k[A]^2$? If so, why are they the same when in fact two molecules of A produce one molecule of B?


I'm really confused about this part. Can anyone explain why coefficient doesn't play a role in this calculation? Thanks!




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