Saturday, November 25, 2017

physical chemistry - Why can't helium be solidified at 'ordinary' pressures?


According to the UC Davis ChemWiki Chemistry of Helium, helium has a comparatively unusual property, specifically:



Helium is the only element that cannot be solidified by lowering the temperature at ordinary pressures.



'Ordinary' referring to standard air pressure (1 atmosphere). In order to solidify, there needs to be a corresponding pressure increase, with a projected density of:




$0.187 \pm 0.009~\mathrm{g~mL^{-1}}$ at $0~\mathrm{K}$ and $25~\mathrm{bar}$.



So why can't helium be solidified at 'ordinary' pressures?



Answer



When the temperature of helium gas is decreased to about 5.2 K, a phase transition to ordinary liquid helium ($\ce{He}$ I) occurs. The behavior of this liquid phase is normal and identical to any other liquid phase.


As temperature is decreased more (at moderate pressures), helium does not solidify. In fact, it undergoes a phase change to a second liquid phase known as $\ce{He}$ II at a temperature of approximately 2.17 K. As shown in the phase diagram below, the $\ce{He}$ II phase persists until absolute zero. Due to quantum effects, $\ce{He}$ II has remarkably unique properties. It is considered a superfluid.


enter image description here


For more details, please click here. Pressure is required to produce solid helium (25 atmospheres or more), because of the small mass and extremely weak forces between the helium atoms.


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