Sunday, November 26, 2017

equilibrium - How to calculate the equivalent mass of Na2S2O3?



Let us consider the following reaction


IX2+2NaX2SX2OX32NaI+NaX2SX4OX6


Now, in order to calculate the equivalent mass of NaX2SX2OX3, first I need to calculate it's n-factor which turns out to be 0.5 because the oxidation state of S in NaX2SX2OX3 is +2 whereas in NaX2SX4OX6 it is +2.5.And the n-factor of IX2 is 1. So, the equivalent mass of NaX2SX2OX3 is


molecular mass0.5 And Iam confused with the following half-reactions: IX2+2e2IX 2SX2OX3X2SX4OX6X2+2e I appreciate any help in order to solve a problem using milliequivalents?





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