Wednesday, November 15, 2017

inorganic chemistry - Why does copper(II) sulfate react with ammonia?


We've done preparation of Tetraamminecopper(II) sulphate [Cu(NHX3)X4(HX2O)Xn]SOX4 using copper sulphate and 50% ammonia solution. Initially, a pale blue color of Cu(OH)X2 appeared with turbidity then after a dark blue color solution is obtained. It is a substitution reaction Initially, why formation of Cu(OH)X2 is taking place ??


Is initially NH3 acting as a base and ripping off the proton from the complex [Cu(HX2O)X6]X2+? Then on the further increment of the concentration of NHX3, it starts to act as Nucleophile?? My high school teacher taught me that acid-base reactions are always fast, so in this example is everything is about kinetics? What is the role of the thermodynamics? From where can I get a quantitative explanation with proper data?




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