Why is tetracyanonickelate, [Ni(CN)X4]X2− square planar?
- CN, for being a strong field, would not follow Hund's rule.
- the central atom Ni would have a +2 charge so its configuration would change from 3dX8 4sX2 to 3dX8 4sX0
- Using the statements above and using crystal field theory I get its hybridization as dspX3, which suggests that its shape must be trigonal bipyramidal while it is not.
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