Tuesday, February 26, 2019

coordination compounds - Why is tetracyanonickelate square planar?



Why is tetracyanonickelate, [Ni(CN)X4]X2 square planar?




  • CN, for being a strong field, would not follow Hund's rule.


  • the central atom Ni would have a +2 charge so its configuration would change from 3dX8 4sX2 to 3dX8 4sX0

  • Using the statements above and using crystal field theory I get its hybridization as dspX3, which suggests that its shape must be trigonal bipyramidal while it is not.




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