Friday, February 2, 2018

orbitals - Why does hybridization produce a more stable configuration?


My text, and the other sources I've checked, include information on the effects, and kinds, of hybridized orbitals; however, they do not explain what properties of hybridized bonds conduce greater stability.


Why does hybridization produce a (lower energy) more stable configuration?



Answer




What causes orbital hybridization?




Hybridization only occurs in response to bond formation, that is an atom will not just spontaneously hybridize on its own. Further, an atom will only hybridize if hybridization leads to the formation of a more stable (lower energy) molecule.


Nature is very efficient at exploring the energy surface and finding whatever energy minimum is available. For example, ammonia ($\ce{NH3}$) is roughly a tetrahedron with $\ce{H-N-H}$ bond angles around 109.5° (the tetrahedral angle) using (roughly) $\mathrm{sp^3}$ hybridized orbitals. For ammonia, mixing (hybridizing) it's $\mathrm{2s}$ and three $\mathrm{2p}$ orbitals to form four $\mathrm{sp^3}$ hybridized orbitals that are used to form three $\ce{N-H}$ bonds and one lone pair orbital produces a more stable molecule than if it were not hybridized. On the other hand, the analogue phosphine ($\ce{PH3}$) chooses to remain roughly unhybridized, using p-orbitals to form its $\ce{P-H}$ bonds with a resultant $\ce{H-P-H}$ bond angle around 90°. Bond strengths, steric factors, etc. all play into determining whether a hybridized or unhybridized structure will be the more stable.


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