Tuesday, February 27, 2018

organic chemistry - Reaction of ethylene glycol with PI₃ (P + I₂)


We know that $\ce{2P + 3I2 -> 2PI3}$


Ethylene glycol reacts with $\ce{PCl3}$ to give ethylene dichloride, but why does it gives ethylene when it reacts with $\ce{P + I2}$?


I don't really know why it happens so as it is quite contradictory because in case of primary alcohols, corresponding iodoalkane is formed.




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