Sunday, December 29, 2019

sp2 hybridization Group V elements


I'm confused about sp2 hybridization in the formation of NOX3X ion. Valence electrons of N are (2s)2 and (2p)3.



Is one of 2s electrons kicked up to one of the 2p orbitals, and then the remaining 2s electron hybridized with the two remaining 2p orbitals which have unpaired electrons? If so, that gives sp2 orbitals to bond with p orbitals of the oxygen atoms. However, there is now that remaining unhybridized p orbital of nitrogen, which has 2 electrons, so how can it be involved in π bonding?


I would appreciate someone explaining this. I'm sure I'm missing something simple, but my book doesn't have an explanation of sp2 hybridization for Group V elements.




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