Monday, June 3, 2019

redox - Calculating n factor of SO2


I'm having a hard time trying to figure out n factor of $\ce{SO2}$ in the reaction


$$\ce{FeS2 + O2 → Fe2O3 + SO2}\qquad \text{(unbalanced)}$$


To balance it, I saw that in 1 mole of $\ce{FeS2}$, it looses a net total of 11 moles of electrons, while $\ce{O2}$ gains 4 moles of electrons per mole of it. That means they will have to react in a $4:11$ ratio, from this, the equation balances out to


$$\ce{4 FeS2 + 11 O2 → 2 Fe2O3 + 8 SO2}$$


The question was (wrt to this equation), what will be the equivalent weight of $\ce{SO2}$, if the molecular weight of $\ce{SO2}$ is $M$?


This means I will need the $n$ factor of it to divide by $M$,


I tried to reverse this reaction


$$\ce{2 Fe2O3 + 8 SO2 → 4 FeS2 + 11 O2}$$



But the problem is that now it's hard to tell from which $\ce{O}$ atoms (of the now-products), the oxidation state is getting changed to $\pm0$ (zero). It's now confusing me.


The answer is given as $M/5$. I don't know why, according to the solution they only concidered the oxidation number change of $\ce S$ while ignoring the others, I don't think it's right.




No comments:

Post a Comment

digital communications - Understanding the Matched Filter

I have a question about matched filtering. Does the matched filter maximise the SNR at the moment of decision only? As far as I understand, ...