Tuesday, June 18, 2019

experimental chemistry - Why isn't dry CaCl₂ used to dry HCl gas instead of concentrated sulfuric acid?


In our chemistry books, it is said that concentrated sulphuric acid is used to dry HCl gas.


But, concentrated sulphuric acid is a strong oxidising agent so, why isn't HCl gas oxidised to HX2O and chlorine gas?


Why dry CaClX2 (Calcium Chloride) isn't used as drying agent?


[Note: CaClX2 have no reaction with HCl as they both have chloride ion in common]



Answer



Why does concentrated HX2SOX4 oxidise? Due to the nascent oxygen it gives: HX2SOX4SOX2+HX2O+[O]



Now, if you want HCl to be oxidised, the following reaction must exist: HCl+[O]HClO


But, you can observe that the reactionHClOHCl+[O] can't be backward under normal conditions (you probably have read this reaction in the bleaching action of bleaching powder). So, fortunately, you can safely use HX2SOX4 in this purpose...and take its advantage to CaClX2, as agha rehan abbas and Molx mentioned.


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