So looking at the Wikipedia pages of sulfur tetrafluoride and silicon tetrafluoride, the melting points are −121 °C and −90 °C respectively, and so SiFX4 has the higher melting point. However, their boiling points are −38 °C and −86 °C, respectively, giving SFX4 the higher boiling point.
I can justify that SFX4 has the higher boiling point because it is more polar since its Lewis structure has a lone pair on the sulfur atom, and so it experiences greater dipole-dipole forces. However, why does SFX4 have a lower melting point?
Answer
High symmetry molecules fit into crystal lattices especially well (higher m.p.), but are volatile for having fewer van der Waals interactions (lower b.p.).
Compoundm.p./∘Cb.p./∘Cpentane−13036.1isopentane−16027.2neopentane−189.5octane−571252-methylheptane−1101172,2,4-trimethylpentane−107992,2,3,3-tetramethylbutane101107cubane131133(sub. at r.t.)*decane−30174isodecane−75167adamantane270sub.
* sub. — sublimes; r.t. — room temperature.
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