Thursday, September 19, 2019

inorganic chemistry - Why does the second electron affinity has an opposite sign of the first one?



Many first electron affinities are positive, indicating a favourable process, but the corresponding second electron affinities are negative. For example, the first and second electron affinities of oxygen are $+141$ and $-780~\mathrm{kJ~mol^{-1}}$ respectively. Why is this so?




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