Sunday, May 5, 2019

inorganic chemistry - In which state does the bifluoride anion exist?



Statement 1. The HFX2X ions exist in solid state and also in liquid state but not in aqueous state.
Statement 2. The magnitude of hydrogen bonding between HF is weaker than that between HF and HX2O



  1. Both are correct and 2 explains 1

  2. Both are correct but 2 does not explain 1

  3. 1 is correct and 2 false

  4. 2 is correct and 1 false




The answer given is 1.


I know the second statement to be true. ΔH(HFO)=4045 kJ/mol,ΔH(HFF)=2023 kJ/mol


But I am completely unsure about statement 1 and the relation of the two statements. I think the existence of the afforementioned ion in aqueous solution must not be absent, as I have read somewhere that this ion acts as the conjugate base of the molecule HX2FX2 which dissociates into hydrofluoric acid.




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