Thursday, May 23, 2019

energy - Can Rydberg constant be in joules?


In my textbook (Chemistry Part - I for Class XI published by NCERT), there is an equation for the energy of an electron in an energy state: En=RH(1n2)

and there is a paragraph below it with the following text:



where RH is called Rydberg constant and its value is 2.18×1018 J.



There is another section with the expression for the wavenumber (¯ν): ¯ν=109677(1n211n22) cm1

with a paragraph with the following text:




The value 109677 cm1 is called the Rydberg constant for hydrogen.



I checked online and found that in most (all) websites (incl. Wikipedia), the value of Rydberg constant is 109677 cm1. But when I searched for its value in joules, I found this website with the value of Rydberg constant =2.18×1018 J.


How can Rydberg constant be written in joules?



Answer



Authors may be sloppy about notation in this matter. I recommend considering RH10973 cm1 and Ry2.181018 J, noting Ry=hcRH. Units of wavenumbers (cm1) and energy are often considered interchangeable in practice because they are proportional to each other by the constant value hc.


In my notes, I would always be sure to write RH or Ry to explicitly remind myself "which" Rydberg constant I was using (in fact I merged the R and y into a single symbol because I didn't like the suggestion of multiplication.)


Note also that there is a unit of energy known as a Rydberg, with 1 Ry=Ry=hcRH.


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