In my textbook (Chemistry Part - I for Class XI published by NCERT), there is an equation for the energy of an electron in an energy state: En=−RH(1n2)
where RH is called Rydberg constant and its value is 2.18×10−18 J.
There is another section with the expression for the wavenumber (¯ν): ¯ν=109677(1n21−1n22) cm−1
The value 109677 cm−1 is called the Rydberg constant for hydrogen.
I checked online and found that in most (all) websites (incl. Wikipedia), the value of Rydberg constant is 109677 cm−1. But when I searched for its value in joules, I found this website with the value of Rydberg constant =2.18×10−18 J.
How can Rydberg constant be written in joules?
Answer
Authors may be sloppy about notation in this matter. I recommend considering RH≈10973 cm−1 and Ry≈2.18⋅10−18 J, noting Ry=hc⋅RH. Units of wavenumbers (cm−1) and energy are often considered interchangeable in practice because they are proportional to each other by the constant value hc.
In my notes, I would always be sure to write RH or Ry to explicitly remind myself "which" Rydberg constant I was using (in fact I merged the R and y into a single symbol because I didn't like the suggestion of multiplication.)
Note also that there is a unit of energy known as a Rydberg, with 1 Ry=Ry=hc⋅RH.
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