I am unable to rationalise the order of increasing bond length in COX3X2−, CO and COX2. Having gone through the factors affecting bond length in two different books, my approach to the problem was:
CO has bond order 3 while carbonate and COX2 have bond order 4 so CO should have longest bond length.
COX2 is sp hybridized while COX3X2− is sp2 hybridized. Since carbonate has lesser s character and therefore it should have a greater bond length than COX2
Thus, COX2<COX3X2−<CO
However, I am unsure about my method. What would be the best approach to determine the relative bond length order?
Answer
Actually, in regard to bond length, you should be looking at the bond order of a single bond within the molecule. The bond order is 2, not 4, for COX2, and the bond order for the carbonate ion is somewhere between 1 and 2 due to resonance. Thus, the carbonate ion has the longest bond length, followed by carbon dioxide, and finally carbon monoxide.
No comments:
Post a Comment