Thursday, January 9, 2020

How is it that the equilibrium constant does not depend on the mechanism?


For a reaction of the form



aA+bBcC+dD


the equilibrium constant is


Kc=[C]c[D]d[A]a[B]b


regardless of the mechanism of the reaction. Why is this the case?


I've seen derivations that use a reaction in one elementary step to demonstrate this, but this obviously doesn't work in general. The sample reaction used was NX2OX42NOX2.




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