In March's Advanced Organic Chemistry (6th ed.), it's stated that the above two are atropisomers. I don't get why is it so. How is the topmost $\ce{C}$ locked in its place? Surely, there's steric hindrance due to presence of two methyls but how does that prevent rotation? It can certainly rotate with the methyls being "rigid" in their positions. Also, are they chiral? I believe they aren't because they are superimposable mirror images.
Subscribe to:
Post Comments (Atom)
digital communications - Understanding the Matched Filter
I have a question about matched filtering. Does the matched filter maximise the SNR at the moment of decision only? As far as I understand, ...
-
As far as I know, living people can positively affect the dead. This is the reason we say Kaddish and learn Mishnayos for the souls of the ...
-
Are there any statistics as to what percentage of Chabad still believes that their Rebbe is the Messiah? Is it the majority or simply a very...
-
I have been wondering if Japanese language include letter P. I have actually seen words like Pan in Japanese which means bread, but then I f...
No comments:
Post a Comment