Is there any way of predicting whether a precipitate will be colored? I know that for solutions, transition metal ions with unfilled d-orbitals will have color because of d-orbital splitting in the complex ions. However, this isn't applicable to precipitates because those are just ionic solids, not complex ions.
For example, $\ce{PbI2}$ is a yellow solid, and $\ce{Al(OH)3}$ is white. Is there a way to predict that $\ce{PbI2}$ will be colored while $\ce{Al(OH)3}$ will not be, or is it something we have to memorize to know?
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