Tuesday, April 23, 2019

ionic compounds - Predicting color of precipitate


Is there any way of predicting whether a precipitate will be colored? I know that for solutions, transition metal ions with unfilled d-orbitals will have color because of d-orbital splitting in the complex ions. However, this isn't applicable to precipitates because those are just ionic solids, not complex ions.


For example, PbIX2 is a yellow solid, and Al(OH)X3 is white. Is there a way to predict that PbIX2 will be colored while Al(OH)X3 will not be, or is it something we have to memorize to know?




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