Sunday, February 2, 2020

inorganic chemistry - Reaction of chlorine with hot/cold solution of hydroxide


When chlorine reacts with cold solution of say potasium hydroxide, the disproportionation goes to lower oxidation states:


ClX2+2KOHKCl+KClO+HX2O



Whilst with hot solution the oxidation state of chlorine goes up to +V:


3ClX2+6KOHKClOX3+5KCl+3HX2O


Why is that? Does the heat make the oxidation to higher ox. states easier?




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