When chlorine reacts with cold solution of say potasium hydroxide, the disproportionation goes to lower oxidation states:
ClX2+2KOH⟶KCl+KClO+HX2O
Whilst with hot solution the oxidation state of chlorine goes up to +V:
3ClX2+6KOH⟶KClOX3+5KCl+3HX2O
Why is that? Does the heat make the oxidation to higher ox. states easier?
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