Friday, January 11, 2019

What is the meaning of the "dot" notation in chemical formulas?


For example for 4 given elements A,B,C,D, what's the meaning of $\text{AB} \cdot x \text{CD}$?



Answer




By writing $\ce{AB.xCD}$ chemists mean that there are CDs are found in the crystalline framework of AB. The most common example of this is water trapped inside the crystal structure of ionic compounds. (See water of crystallization in wikipedia)


An example that's often taught is $\ce{CuSO4.5H2O}$. See that 5 that's a representative of $x$? It means that water can be bound only wit intermolecular interactions, but it exists in the structure in a stoichiometric ratio.


CuSO4 hydrate picture


Source


Also, according to this article



In summary, when a dot is used to break a formula into subunits, it may signify ignorance of how the subunits are structurally related, as in our inorganic example; or it may correspond to actual significant structural subunits, as in our organic example; or it may represent the combining ratios of the binary starting materials required for the synthesis of the compound, as in our phase diagram example.



As a result, for example in direct addition reactions, where there is ignorance about the structural relation of the compounds, we use a dot.


No comments:

Post a Comment

digital communications - Understanding the Matched Filter

I have a question about matched filtering. Does the matched filter maximise the SNR at the moment of decision only? As far as I understand, ...